To enable remote powershelling with servers not in the same domain as the client machine you will need to perform the following steps:
On the server PC type:
Enable-PSRemoting

On the client PC type:
Server IP 192.168.3.100
set-item wsman:\localhost\client\trustedhosts -value 192.168.3.100
$cred = get-credential 192.168.3.100\administrator
enter-pssession -computername 192.168.3.100 -credential $cred
